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CITRONELLOL 950
| Parameters |
Specifications |
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PRODUCT CODE
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COL
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CAS No.
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106-22-9 & 26489-01-0
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FL No.
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2309
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EINECS
|
203-375-0 & 247-737-6
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Kosher
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Yes
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Olfactive note
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Fresh, floral-rose, slightly citrus
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Description
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Starting raw material for many citronellyl esters and hydroxydihydro citronellol.
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Application
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Widely used in perfume compositions, particularly for rose notes. Also used in soap and household product fragrances.
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Recommended use level
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25 ppm to 50%
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Natural status
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Nature identical
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Tenacity
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56 Hrs at 100%
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Boiling point
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225 0C @ 760 mm Hg
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Flash point
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>93.33 0C
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Solubility in Alcohol
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1 ml soluble in 2 ml 70% Alcohol
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Standard packing
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170 kgs GI Barrels (customized packing available)
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Appearance:
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Colorless to pale yellow clear liquid
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Purity (GLC %):
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95% min. as C10H20O
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Formula:
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C10H20O
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Molecular Weight:
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156.27 gm/mol
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Chemical Name:
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3,7-dimethyl-6-octen-1-ol
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OLFACTIVE NOTE
- Fresh, Floral-Rose, Slightly citrus
- Widely used in many perfume compositions, particularly for rose notes.
- It is the starting raw material for several citronellyl esters and for hydroxydihydrocotronellol.
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PHYSICO CHEMICAL PROPERTIES
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| APPEARANCE |
COLORLESS TO PALE YELLOW CLEAR LIQUID |
| PURITY (GLC %) |
95 % min. as C10H20O |
| BOILING POINT |
225 0C @ 760 mm Hg |
| FLASH POINT |
93.330C |
| SPECIFIC GRAVITY |
0.8500 – 0.860 @ 25 0C |
| REFRACTIVE INDEX |
1.4500 – 1.4600 @ 20 0C |
| TENACITY |
56 Hrs at 100% |
| SOLUBILITY IN ALCOHOL |
1 ml soluble in 2 ml 70% Alcohol |
| SOLUBILITY IN WATER |
105.5 mg/L @ 25 0C (est) |
| ACID VALUE |
1 Max KOH/gm |
| VAPOUR PRESSURE |
0.02 mm/Hg @ 25 0C |
| VAPOUR DENSITY |
5.4 (Air=1) |
| Log P (o/w) |
3.91 |
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SYNONYM
-
(+)-Citronellol, (+/-)- Citronellol, J-Citronellol, dl-Citronellol,
Rhodinol, 3,7-dimethyloct-6-en-1-ol, 2,6-dimethyl-2-octen-8-ol,
3,7-dimethyl-6-octen-1-ol.
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USE LEVEL
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| FLAVOR |
Up to 25 ppm |
| FRAGRANCE |
Up to 25 % |
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REGULATORY INFORMATION
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| CAS |
106-22-9 & 26489-01-0 |
| FEMA |
2309 |
| EINECS |
203-375-0 & 247-737-6 |
| CoE |
59 |
| FL No. |
02.011 |
| JECFA No. |
1219 |
| EXPORT TARIFF CODE |
2909.22.5010 |
| FOOD CHEMICAL CODEX |
YES |
| FDA RAGULATION |
21 CFR 172.515 |
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PACKING:
- AS PER CUSTOMER’S REQUIREMENT
STORAGE:
- Stable when stored in tightly sealed GI, HDPE, or Aluminum packing.
- Keep in cool (7-320C) and dry area, away from direct heat and light.
- Shelf life of 24 months from the date of manufacturing.
- If stored for more than 12 months, quality should be checked before use.
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Section 1: IDENTIFICATION OF THE SUBSTANCE AND OF COMPANY
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| Product Name |
Citronellol 950 |
| Chemical Name |
3,7-dimethyloct-6-en-1-ol
|
| CAS No. |
106-22-9 & 26489-01-0 |
| EC/EINECS No. |
203-375-0 & 247-373-6 |
| Usage |
In flavors and fragrances, Ingredient for manufacturing mixtures,
Not intended for final consumer. |
| Manufacturer |
Breeze Intermediates Pvt. Ltd.
Z-39, Dahej SEZ, Dahej, Ta. Vagra, Dist. Bharuch (Guj.) India
Tel.: +91 02642 260091
Email: info@breezeipl.com, breezeipl@yahoo.in |
| Emergency telephone no. |
+91 02642 260091, +91 9825107638, +91 9825031257 |
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Section 2: HAZARDS IDENTIFICATION
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| Classification as per EC No. 1272/2008
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Skin corrosion/irritation, Hazard Category 2; Sensitisation — Skin, Hazard
Category 1; Hazardous to the aquatic environment — Chronic Hazard, Category 2. |
| Classification as per
Dir. 67/548/EEC |
Hazard Symbol: Xi-Irritant
N: Hazardous for environment |
| OSHA Hazard |
Irritant |
| Label elements including
precautionary statement |
Pictogram: 
Siganl word:-Warning
Hazard statements:-
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H411: Toxic to aquatic life with long lasting effects
Precautionary statements:-
P273: Avoid release to the environment.
P280: Wear protective gloves/eye protection/face protection.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P3333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage
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| Risk Phrases |
Refer to section 15: Regulatory information |
| HMIS
Classification |
Health hazard: 2 Flammability: 0 Physical hazards: 0 |
| NFPA Rating |
Health hazard: 2 Fire: 0 Reactivity Hazard: 0 |
| Potential Health Effects
Classification |
Inhalation: May be harmful if inhaled.Causes respiratory tract irritation.
Skin: May be harmful if absorbed through skin. Causes skin burns.
Eyes: Causes eye irritation.
Ingestion: harmful if swallowed.
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| Other Hazards |
The product does not contain substances included in the Substances of Very High
Concern list (> 0.1 % w/w). |
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Section 3: INFORMATON ON INGREDIENTS
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| Concentration of the constituent (% wt/wt)
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95-100% |
| Chemical Name
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3,7-dimethyloct-6-en-1-ol |
| Chemical Entity |
 -unsaturated (alkene or alkyne) straight-chain and branched-chain aliphatic
primary alcohols/aldehydes/acids, acetals and esters with esters containing -
unsaturated alcohol and acetal containing -unsaturated alcohols or aldehydes.
No aromatic or heteroaromatic moiety as a component of an ester or acetal.
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| Molecular Formula |
C10 H20O (M.W.= 156.27 g/mol) |
| CAS No. |
106-22-9 & 26489-01-0 |
| EC/EINECS No.
|
203-375-0 & 247-373-6 |
| FEMA |
2309 |
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Section 4: FIRST AID MEASURES
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| Consumption
(Ingestion)
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If swallowed, rinse mouth with water (only if the person is conscious).
Seek medical advice immidiately. Do not induce vomiting. |
| Eye Exposure
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First rinse with plenty of water for several minutes (remove contact lenses if easily
possible), then take to a doctor. |
| Inhalation |
If inhaled, remove person to fresh air.
If not breathing give artificial respiration.
If breathing is difficult, give oxygen. |
| Skin Exposure |
Wash immediately affected area with soap and plenty of water.
Seek medical advice if irritation, pain, swelling, lacrimation or photophobia persists. |
| Most important
symptoms and
effects, both acute
and delayed |
Symptoms on inhalation: Choking, drowsiness, respiratory disruptions.
Symptoms on eye contact: Irritation, reddening.
Symptoms on skin contact: Irritation, stinging.
Symptoms on ingestion: queasiness, stomach aches. |
| Immediate medical
attention special
treatment
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Not applicable. |
| Others |
Take Risk and Safety Phrases (section 15) into account |
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Section 5: FIRE-FIGHTING MEASURES
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| Extinguishing
Media
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Water spray, Alcohol-resistant foam, carbon dioxide, dry chemical powder or
appropriate foam. For safety reasons do not use full water-jet. |
| Hazards arising
from the substance
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Not applicable. |
| Combustible Liquid |
Keep away from source of heat, flame or spark.
Cool endengered drums with water. |
| Advices for
firefighters |
In case of fire on the surrounding, follow the instructions:
1-Closed containers may build up pressure at elevated temperatures.
2-Avoid inhalation of generated fumes or vapors. Use apropriate respiratory equipment.
3-Do not allow the spillage of the fire extinguishing to sink into a drainage system or
water area. |
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Section 6: ACCIDENTAL RELEASE MEASURES
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| Personal precautions,
protective equipment and
emergency procedures
|
Handle the product using protective gloves resistant to the the chemicals
exposed. Avoid contact with skin and inhalation of its vapours or smoke.
Maintain adequate ventilation in the working area after spilling. |
| Environmental precautions
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To avoid possible contamination of the environment, Do not discharge into any
drains, surface waters or groundwaters |
| Methods and material for
containment and cleaning
up |
Cover with an inert, inorganic, non-combustible absorbent material
(e.g. dry-lime, sand, soda ash). Place in covered containers using nonsparking
tools and transport outdoors. Avoid open flames or sources of ignition
(e.g. pilot lights on gas hot water heater). Ventilate area and wash spill site
after material pickup is complete. Dispose of in accordance with current laws
and regulations. |
| Reference to other sections
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Refer to section 13 Disposal considerations
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Section 7: HANDLING AND STORAGE
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Precautions
for safe
handling
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Keep away from food, drink and animal feedingstuffs. When using do not smoke. Avoid
contact with skin and eyes.
Handle in accordance with good industrial hygiene and safety practice. |
| Condition for
Storage
|
Should be stored in tightly sealed and preferably full containers in a cool, well-ventilated, dry
place, out of direct rays of the sun, Away from areas of high fire hazard, & should be
periodically inspected. Incompatible materials should be isolated from each other. |
| Specific end
use(s) |
Not available |
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Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
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Control parameters
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Declaration of substances is not required. |
| Exposure controls
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Personal protection equipment: Use personal protection equipment according to
Directive 89/686/EEC.
Eye/Face protection: Chemical safety goggles are recommended. Wash
contaminated goggles before reuse.
Respiratory Protection: Use personal breathing apparatus whenever deemed
necessary.
Skin Protection: Avoid contact with skin. Compatible chemical-resistant gloves
are recommended. Wash contaminated gloves before reuse.
Engineering Controls-Ventilation: The areas where the product is handled and
stored should be adequately ventilated.
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Section 9: PHYSICAL AND CHEMICAL PROPERTIES
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Appearance |
Colorless to pale yellow clear liquid |
| Odor
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Characteristic, fresh, floral, rose
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| pH value |
No data available |
| Boiling point
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225 oC @ 760 mmHg
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| Flash point (closed cup)
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>93.33 oC.
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| Vapour Pressure |
0.200000 mm/Hg @ 25.00 oC. |
| Vapour Density
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5.4 (Air=1)
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| Solubility in Water |
105.5 mg/L @ 25.00 oC |
| Solubility in Alcohol
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1 gm soluble in 1 ml 70% Alcohol
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| Specific Gravity |
0.850~0.860 @ 25.00 oC. |
| Partition Coefficient (Octanol/Water)
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3.91
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Section 10: STABILITY AND REACTIVITY
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Chemical stability
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Stable under normal operational condition.
Oxidized slowly on exposure to heat, light and air. |
| Reactivity
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Heat, excessive heat, open flames and other sources of ignition.
Strong oxidizing agents, strong reducing agents. |
| Incompatibility |
Does not react with water. Avoid contact with strong oxidizing mineral acids,
strong reducing agents. |
| Hazardous decomposition
products
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Hazardous combustion or decomposition products:
carbon oxides and other unidentified organic compound. |
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Section 11: TOXOLOGICAL INFORMATION
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Acute toxicity
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Oral Toxicity (LD50 ): Oral-Rat 3450 mg/kg
Dermal Toxicity (LD50): Skin-Rabbit 2650 mg/kg |
| Inhalation Toxicity (LD50)
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Not Determined |
| Skin corrosion/irritation |
Skin - Human - Skin irritation - 48 h |
| Human Experience
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No data available |
| Serious eye damage/eye irritation |
No data available |
| Respiratory or skin sensitization |
No data available |
| Germ cell mutagenicity
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No data available |
| Carcinogenicity |
IARC: No component of this product present at levels greater than
or equal to 0.1% is identified as probable,possible or confirmed
human carcinogen by IARC.
ACGIH: No component of this product present at levels greater than
or equal to 0.1% is identified as a carcinogen or potential
carcinogen by ACGIH.
NTP: No component of this product present at levels greater than or
equal to 0.1% is identified as a known or
anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than
or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
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| Reproductive toxicity
|
No data available. Overexposure may cause reproductive disorder/s |
Specific target organ toxicity
single exposure (GHS) |
Inhalation - May cause respiratory irritation. |
Specific target organ toxicity
repeated exposure (GHS)
|
No data available |
| Aspiration hazard |
No data available |
| Potential health effects
|
Inhalation: May be harmful if inhaled. Causes respiratory tract
irritation.
Ingestion: Harmful if swallowed.
Skin: May be harmful if absorbed through skin.
Causes skin irritation.
Eyes: Causes eye irritation. |
| Signs and Symptoms of Exposure |
Cough, Shortness of breath, Headache, Nausea, Vomiting |
| Additional Information
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RTECS: RH3400000 |
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Section 12: ECOLOGICAL INFORMATION
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General
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Prevent contamination of soil, ground and surface waters.
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| Acute aquatic Toxicity
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LC50 - Leuciscus idus (Golden orfe) - 10.0 - 22.0 mg/l - 96 h |
| Persistence and degradability |
Not available |
| Bioaccumulative potential
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Bioconcentration Factor |
| Mobility in soil |
No data available |
| PBT and vPvB assessment
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Bioconcentration Factor |
| Other adverse effects |
Do not allow the material to enter streams, sewers or other waterways |
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Section 13: DISPOSAL CONSIDERATION
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| Product Disposal
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Dispose of according all federal, state, and local environmental regulations.
Contact a licensed professional waste disposal service to dispose of this material.
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| Packaging |
Do not re-use empty containers. Empty residue into a suitable disposal site.
Contaminated packaging should be disposed of as unused product. |
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Section 14: TRANSPORT INFORMATION
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| International Carriage of Dangerous Goods by Road (ADR)
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| UN No. |
UN3082 |
| Proper Shipping Name
|
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Contains 3,7-Dimethyloct-6-en-1-ol)
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| Packing Group |
III |
| Class
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9
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| Tunnel restriction code |
E |
| Label
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| Air Transport (ICAO/IATA) |
| UN No.
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UN3082
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| Proper Shipping Name
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ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Contains 3,7-Dimethyloct-6-en-1-ol)
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| Class |
9 |
| Packing Group
|
III
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| Sea Transport (IMDG) |
| UN No.
|
UN3082
|
| Proper Shipping Name |
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (Contains 3,7-Dimethyloct-6-en-1-ol) |
| Class
|
9
|
| Packing Group |
III |
| EmS
|
F-A, S-F
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| Marine Pollutant |
Yes |
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Section 15: REGULATORY INFORMATION
|
| Safety, health and
environmental
regulations/legislation
specific for the
substance
|
Substance(s) is (are) either included in EINECS, ELINCS, NPL inventories or
exempted |
| OSHA Hazard
|
Xi-Irritant |
| Risk Phrases |
R 36/38 - Irritating to skin and eyes.
R 43 - May cause sensitisation by skin
contact.
R 51/53 - Toxic to aquatic organisms, may cause long-term adverse effects
in the aquatic environment.
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| Safety Phrases
|
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water
and seek medical advice.
S 37/39 - Wear suitable gloves and eye/face protection.
S 61 - Avoid release to the environment. Refer to special instructions/safety data
sheet.
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| WGK Germany |
1 |
| Chemical safety
assessment
|
Not available |
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Section 16: OTHER INFORMATION
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|
Hazardous materials identification system
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Fire:1 Health:2 Reactivity: 0 Personal Protection:B
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This material should be used for industrial purposes only. |
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DISCLAIMER
- The information in this MSDS is from available published sources and is believed to be accurate. No warranty,
express or implied, is made and BREEZE INTERMEDIATES Pvt. Ltd. assumes no liability resulting from the use
of this MSDS. The user must determine suitability of this information for his application. This
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