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BENZYL ACETONE
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Parameters
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Specifications
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PRODUCT CODE
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BA
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CAS No.
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2550-26-7
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FL No.
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07.194
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EINECS
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219-847-4
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Kosher
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Yes
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Olfactive note
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Sweet-flowery, herbal, floral-green
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Description
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Fresher than Benzyl Acetate, more lasting.
Found in nature as a volatile constituent of cocoa. |
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Application
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Used in perfumes as a modifier for Benzyl Acetate.
Particularly used in soap perfumes.
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Recommended use level
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25 ppm to 2%
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Natural status
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Nature identical
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Tenacity
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172 Hrs
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Boiling point
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235 0C @ 760 mm Hg
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Flash point
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97.78 0C
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Solubility in Alcohol
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Soluble
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Standard packing
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210 kgs GI Barrels (customized packing available)
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Appearance:
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Colorless to pale yellow clear liquid
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Purity (GLC %):
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99% min.
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Benzylidene acetone content
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<0.1%
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Benzyl alcohol content
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<= 0.06%.
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Benzaldehyde content
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<= 0.02%
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4-Phenyl-2-butanol content
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<= 0.1%
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Formula
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C10H12O
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Molecular Weight:
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148.21 gm/mol
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Chemical Name:
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4-phenylbutan-2-one
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OLFACTIVE NOTE
- Sweet-Flowery, Herbal, Floral-Green
- Strong Floral green odor, Fresher than Benzyl Acetate, more lasting. Some what Buttery.
- Used in perfumes as a modifier for Benzyl Acetate, particularly used in soap perfume.
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PHYSICO CHEMICAL PROPERTIES
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APPEARANCE
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COLORLESS TO PALE YELLOW CLEAR LIQUID
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PURITY (GLC %)
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99% min.
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BOILING POINT
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235 oC @ 760 mm Hg
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FLASH POINT
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> 97.78 oC
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SPECIFIC GRAVITY
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0.985 – 0.991 @ 25 oC
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REFRACTIVE INDEX
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1.5090 – 1.5150 @ 20 oC
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TENACITY
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172 Hrs
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VAPOUR PRESSURE
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0.05570 mm/Hg @ 25 oC (est)
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SOLUBILITY IN ALCOHOL
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SOLUBLE
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SOLUBILITY IN WATER
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1625 mg/L @ 25 oC
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ACID VALUE
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1 max. KOH/gm
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Log P (o/w)
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1.96
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SYNONYM:-
- Jasmarol, 4-Phenyl-2-butanone, 1-Phenyl-3-butanone,J-Phenyl ethyl methyl ketone,
Methyl Phenyl ethyl ketone
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USE LEVEL
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FLAVOR
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Up to 25 ppm
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FRAGRANCE
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Up to 2 %
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REGULATORY INFORMATION
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CAS
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2550-26-7
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FEMA
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---
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EINECS
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219-847-4
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CoE
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11182
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FL No.
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07.194
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EXPORT TARIFF CODE
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2914.39.9000
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JECFA No.
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---
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FOOD CHEMICAL CODEX
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NO
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FDA RAGULATION
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---
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PACKING:
- AS PER CUSTOMER’S REQUIREMENT
STORAGE:
- Stable when stored in tightly sealed GI, HDPE, or Aluminum packing.
- Keep in cool (7-320C) and dry area, away from direct heat and light.
- Shelf life of 24 months from the date of manufacturing.
- If stored for more than 12 months, quality should be checked before use.
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Section 1: IDENTIFICATION OF THE SUBSTANCE AND OF COMPANY
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Product Name
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Benzyl Acetone
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Chemical Name
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4-Phenylbutan-2-one CAS No.
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CAS No.
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2550-26-7
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EC/EINECS No.
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219-847-4
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Usage
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In flavors and fragrances. Ingredient in the manufacturing of mixture Not intended
for final consumer.
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Manufacturer
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Breeze Intermediates Pvt. Ltd.
Z-39, Dahej SEZ, Dahej, Ta. Vagra, Dist. Bharuch (Guj.) India
Tel.: +91 02642 260091
Email: info@breezeipl.com, breezeipl@yahoo.in
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Emergency telephone no.
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+91 02642 260091, +91 9825107638, +91 9825031257
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Section 2: HAZARDS IDENTIFICATION
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Classification as per EC No. 1272/2008
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---
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Classification as per Dir. 67/548/EEC
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Substance not classified as dangerous according to the Directive 67/548/EEC
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OSHA Hazard
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Corrosive
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Label elements
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---
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Risk Phrases
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R-38 – Irritating to skin
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HMIS Classification
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Health hazard: 2 Flammability: 1 Physical hazards:
0
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NFPA Rating
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Health hazard: 2 Fire: 1 Reactivity Hazard:
0
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Potential Health Effects Classification
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Inhalation: May be harmful if inhaled. Material is extremely destructive
to the tissue of the mucous membranes and upper respiratory tract.
Skin: May be harmful if absorbed through skin. Causes skin burns.
Eyes: Causes eye burns.
Ingestion: May be harmful if swallowed. Causes burns.
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Other Hazards
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The product does not contain substances included in the Substances of Very High
Concern list (> 0.1 % w/w).
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Section 3: INFORMATON ON INGREDIENTS
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Concentration of
the constituent (% wt/wt)
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98-100%
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Chemical Name
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4-Phenylbutan-2-one
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Chemical Entity
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Aromatic ketones, secondary alcohols and related esters
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Molecular Formula
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C10H20O (M.W.=148.20 g/mol)
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CAS No.
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2550-26-7
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EC/EINECS No.
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219-847-4
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FEMA
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---
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Section 4: FIRST AID MEASURES
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Consumption (Ingestion)
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If swallowed, rinse mouth with water (only if the person is conscious). Seek medical
advice immidiately. Do not induce vomiting.
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Eye Exposure
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First rinse with plenty of water for several minutes (remove contact lenses if easily
possible), then take to a doctor.
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Inhalation
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If inhaled, remove person to fresh air. If not breathing give artificial respiration.
If breathing is difficult, give oxygen.
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Skin Exposure
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Wash immediately affected area with soap and plenty of water.
Seek medical advice if irritation, pain, swelling, lacrimation or photophobia persists.
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Most important symptoms and effects, both acute and delayed
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Symptoms on inhalation: Choking, drowsiness, respiratory disruptions.
Symptoms on eye contact: Irritation, reddening.
Symptoms on skin contact: Irritation, stinging.
Symptoms on ingestion: queasiness, stomach aches.
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Immediate medical attention special treatment
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Not applicable.
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Others
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Take Risk and Safety Phrases (section 15) into account
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Section 5: FIRE-FIGHTING MEASURES
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Extinguishing Media
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Water spray, Alcohol-resistant foam, carbon dioxide, dry chemical powder or appropriate
foam. For safety reasons do not use full water-jet.
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Hazards arising from the substance
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Not applicable.
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Combustible Liquid
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Keep away from source of heat, flame or spark. Cool endengered drums with water.
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Advices for firefighters
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In case of fire on the surrounding, follow the instructions:
1-Closed containers may build up pressure at elevated temperatures.
2-Avoid inhalation of generated fumes or vapors. Use apropriate respiratory equipment.
3-Do not allow the spillage of the fire extinguishing to sink into a drainage system
or water area.
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Section 6: ACCIDENTAL RELEASE MEASURES
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Personal precautions, protective equipment and emergency procedures
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Handle the product using protective gloves resistant to the the chemicals exposed.
Avoid contact with skin and inhalation of its vapours or smoke. Maintain adequate
ventilation in the working area after spilling.
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Environmental precautions
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To avoid possible contamination of the environment, Do not discharge into any drains,
surface waters or groundwaters
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Methods and material for containment and cleaning up
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Cover with an inert, inorganic, non-combustible absorbent material (e.g. dry-lime,
sand, soda ash). Place in covered containers using nonsparking tools and transport
outdoors. Avoid open flames or sources of ignition (e.g. pilot lights on gas hot
water heater). Ventilate area and wash spill site after material pickup is complete.
Dispose of in accordance with current laws and regulations.
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Reference to other sections
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Refer to section 13 Disposal considerations
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Section 7: HANDLING AND STORAGE
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Precautions for safe handling
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Keep away from food, drink and animal feedingstuffs. When using do not smoke. Avoid
contact with skin and eyes. Handle in accordance with good industrial hygiene and
safety practice.
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Condition for Storage
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Should be stored in tightly sealed and preferably full containers in a cool, well-ventilated,
dry place, out of direct rays of the sun, Away from areas of high fire hazard, &
should be periodically inspected. Incompatible materials should be isolated from
each other.
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Specific end use(s)
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Not available
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Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
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Control parameters
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Declaration of substances is not required.
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Exposure controls
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Personal protection equipment: Use personal protection equipment according
to Directive 89/686/EEC.
Eye/Face protection: Chemical safety goggles are recommended. Wash contaminated
goggles before reuse.
Respiratory Protection: Use personal breathing apparatus whenever deemed
necessary.
Skin Protection: Avoid contact with skin. Compatible chemical-resistant gloves
are recommended. Wash contaminated gloves before reuse.
Engineering Controls-Ventilation: The areas where the product is handled
and stored should be adequately ventilated.
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Specific end use(s)
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Not available
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Section 9: PHYSICAL AND CHEMICAL PROPERTIES
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Appearance
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Colorless to pale yellow clear liquid
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Odor
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Characteristic, sweet, aromatic, fruity
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pH value
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No data available
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Boiling point
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235 oC @ 760 mmHg
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Melting point
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-13 oC @ 760 mmHg
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Flash point (closed cup)
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> 97.78 oC.
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Ignition Temperature
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No data available
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Auto Inflammability
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Not Determined
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Explosive Property
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Not Determined
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Oxidizing Property
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Not Determined
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Vapour Pressure
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0.05570 mm/Hg @ 25 oC.
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Vapour Density
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Not Determined
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Solubility in Water
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1625 mg/L @ 25 oC.
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Solubility in Alcohol
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Miscible in Alcohol
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Specific Gravity
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0.985~0.991 @ 25 oC.
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Partition Coefficient (Octanol/Water)
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1.96
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Section 10: STABILITY AND REACTIVITY
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Chemical stability
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Stable under normal operational condition.
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Reactivity
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Heat, excessive heat, open flames and other sources of ignition.
Strong oxidizing agents, strong reducing agents.
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Incompatibility
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Does not react with water. Avoid contact with strong oxidizing mineral acids, strong
reducing agents.
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Hazardous decomposition products
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Hazardous combustion or decomposition products:
carbon oxides and other unidentified organic compound.
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Section 11: TOXOLOGICAL INFORMATION
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Acute toxicity
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Oral Toxicity (LD50): Oral-Rat 3200.00 mg/kg
Dermal Toxicity (LD50): Skin-Rabbit >5000.00 mg/kg
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Inhalation Toxicity (LD50)
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Not Determined
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Skin corrosion/irritation
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Skin- rabbit: sever skin irritation
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Serious eye damage/eye irritation products
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No data available
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Respiratory or skin sensitization
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No data available
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Germ cell mutagenicity
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No data available
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Carcinogenicity
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IARC: No component of this product present at levels greater than or equal
to 0.1% is identified as probable,possible or confirmed human carcinogen by IARC.
ACGIH: No component of this product present at levels greater than or equal
to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.
NTP: No component of this product present at levels greater than or equal
to 0.1% is identified as a known or anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal
to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.
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Reproductive toxicity
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No data available
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Specific target organ toxicity single exposure (GHS)
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No data available
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Specific target organ toxicity repeated exposure (GHS)
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No data available
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Aspiration hazard
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No data available
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Potential health effects
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Inhalation: May be harmful if inhaled. Causes respiratory tract irritation.
Ingestion: Harmful if swallowed.
Skin: May be harmful if absorbed through skin. Causes skin irritation.
Eyes: Causes eye irritation.
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Signs and Symptoms of Exposure
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No data available
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Additional Information
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RTECS: EL9600000
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Section 12: ECOLOGICAL INFORMATION
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General
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Prevent contamination of soil, ground and surface waters. Do not discharge product
unmonitored into the environment.
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Acute aquatic Toxicity
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No data available
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Persistence and degradability
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Not available
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Bioaccumulative potential
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No data available
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Mobility in soil
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No data available
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PBT and vPvB assessment
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Not determined. Not listed on EC’s PBT substances list.
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Other adverse effects
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Do not allow the material to enter streams, sewers or other waterways
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Section 13: DISPOSAL CONSIDERATION
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Product Disposal
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Dispose of according all federal, state, and local environmental regulations. Contact
a licensed professional waste disposal service to dispose of this material.
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Packaging
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Do not re-use empty containers. Empty residue into a suitable disposal site. Contaminated
packaging should be disposed of as unused product.
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Section 14: TRANSPORT INFORMATION
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International Carriage of Dangerous Goods by Road (ADR)
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UN No.
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N/A
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Proper Shipping Name
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Not subject to ADR.
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Packing Group
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---
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Class
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---
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Tunnel restriction code
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---
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Label
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---
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Air Transport (ICAO/IATA)
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UN No.
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N/A
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Proper Shipping Name
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Not restricted (not dangerous good)
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Class
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---
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Packing Group
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---
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Sea Transport (IMDG)
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UN No.
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N/A
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Proper Shipping Name
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Not restricted (not dangerous good)
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Class
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---
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Packing Group
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---
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EmS
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---
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Marine Pollutant
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No
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DOT (US)
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Not dangerous good
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Section 15: REGULATORY INFORMATION
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Safety, health and environmental regulations/legislation specific for the substance
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Substance(s) is (are) either included in EINECS, ELINCS, NPL inventories or exempted
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Hazard Symbol
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Xi- Irritant
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OSHA Hazard
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Corrosive
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Risk Phrases
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R 36/38 - Irritating to skin and eyes. Keep out of the reach of children.
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Safety Phrases
|
S 02 - Keep out of the reach of children.
S 24/25 - Avoid contact with skin and eyes.
S 24 Avoid contact with skin S 36 wear suitable clothing.
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WGK Germany
|
1
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Chemical safety assessment
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Not available
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Section 16: OTHER INFORMATION
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Hazardous materials identification system
|
Fire:1 Health:1 Reactivity: 0 Personal Protection:B
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This material should be used for industrial purposes only.
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DISCLAIMER
- The information in this MSDS is from available published sources and is believed
to be accurate. No warranty, express or implied, is made and BREEZE INTERMEDIATES
Pvt. Ltd. assumes no liability resulting from the use of this MSDS. The user must
determine suitability of this information for his application. This data relates
only to the specific material designated and not to be used in combination with
any other material.
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